海相油气地质2024，Vol.29Issue(1)：81-89,9.DOI:10.3969/j.issn.1672-9854.2024.01.007
辽河坳陷滩海东部地区天然气地球化学特征及有机热成因-无机成因双源模式
Geochemical characteristics of natural gas and dual-source pattern of thermogenic gas and inorganic gas in the eastern offshore of Liaohe Depression
摘要
Abstract
In 2022,a significant gas breakthrough was achieved in the key exploration well(Kuitan-1)located in the Kuihuadao structural belt of the eastern offshore,Liaohe Depression,with high-productivity gas flows in Dongying Formation,Shahejie Member 3,and Jurassic Xiaodonggou Formation.It is worth noting that there are significant differences in methane carbon isotope composition(δ13C1)between the Mesozoic and Cenozoic natural gas formations.Determining the origin of natural gas and its source rock is significant for assessing the potential of natural gas resources and selecting exploration targets.This paper systematically analyzes geochemical data such as the components and stable carbon isotope composition of natural gas samples from the three gas-bearing strata.The results indicate that there are organic thermogenic gas and inorganic gas in the eastern offshore:(1)The natural gas in the Dongying Formation and Shahejie Formation belongs to the coal-type organic thermogenic gas,mainly consisting of methane,the dryness coefficient is at the range of 0.789-0.949.δ13C1 is mainly around-35‰.Natural gas originates from the mature mudstone in the middle and lower part of Shahejie Formation in Gaizhoutan sag,and accumulates during the late Dongying-Minghuazhen periods.According to the empirical formula,Ro of gas source rock ranges from 0.77%to 1.59%.There is a clear indication of migration effects for natural gas in the middle and shallow Dongying Formation,with clearly higher Ro of gas source rock than the mudstone at the same depth.In the deep Shahejie Member 3,it accumulates in situ or with short distance migration,indicated by the similar or slightly higher Ro of gas source rock than the mudstone at the same depth.(2)The natural gas in Jurassic Xiaodonggou Formation is of inorganic origin.It has an average dryness coefficient of 0.991 and is characterized by extremely heavy methane carbon isotope(δ13C1＞-20‰).It's inferred that the natural gas originates from Fischer-Tropsch synthesis in the deep crust or mantle,migrates and accumulates along the deep-seated fault with strike-slip activity during the late Dongying period.These natural gas reservoirs of two genetic types have obvious vertical separation and different accumulation processes.Plays around the Shahejie mature source rocks in the Gaizhoutan sag and the Yingkou-Tong'erbu strike-slip zone are favorable to organic thermogenic gas and inorganic gas respectively.关键词
碳同位素/气体组分/热成因气/无机成因气/费托合成/滩海东部地区/辽河坳陷Key words
carbon isotope/gas components/thermogenic gas/inorganic gas/Fischer-Tropsch synthesis/eastern off-shore/Liaohe Depression分类
能源科技引用本文复制引用
胡英杰,刘兴周,黄双泉,蔡国钢,王延山,李金有,杨光达,侯拓,张东伟..辽河坳陷滩海东部地区天然气地球化学特征及有机热成因-无机成因双源模式[J].海相油气地质,2024,29(1):81-89,9.基金项目
本文受中国石油油气与新能源分公司重大科技专项"辽河油田探区'十四五'油气资源评价"(编号:2023YQX20104)及辽河油田重大科技专项"辽河坳陷深层生烃动力学与天然气资源潜力评价"(编号:2021KJZX-02-02)联合资助 （编号:2023YQX20104）
