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变压吸附分离技术在催化干气乙烯回收中的应用OACSTPCD

Application of pressure swing adsorption separation technology in ethylene recovery from catalytic dry gas

中文摘要英文摘要

介绍了深冷分离技术、吸收分离技术和变压吸附分离技术3种催化干气乙烯回收技术.某石化公司炼油结构调整,催化干气产能由15×104 t/a扩至21×104 t/a,考虑变压吸附分离技术操作简单、无需辅助原料,操作条件变化后装置运行能快速平稳,以及综合能耗低等优势,仍继续采用该技术.根据扩能改造设计原则,将原两段法工艺改为一段法工艺,并将同时处于抽空步骤的塔数由2塔增加为3塔,处于吸附步骤的塔数由4塔增加为5塔.结果表明,产品质量相当时,扩能改造后综合能耗降低约14%,运行指标优于改造前.在减少碳排放的背景下,变压吸附分离技术因综合能耗低于其他技术,更具应用优势.

Three technologies for recovering ethylene from catalytic dry gas,including cryogenic separation,absorption separation,and pressure swing adsorption separation,were introduced.In the context of a structural adjustment of a petrochemical company's refining process,where the catalytic dry gas production capacity increased from 15×104 t/a to 21×104 t/a,pressure swing adsorption technology was chosen due to its advantages,such as simple operation,no need for auxiliary materials,rapid and stable unit operation under changing conditions,and low comprehensive energy consumption.Following the principles of capacity expansion and renovation,the previous two-stage process was converted into a single-stage process.The number of towers in the vacuum step was increased from 2 to 3,and the number of towers in the adsorption step was increased from 4 to 5.The results show that after the capacity expansion and renovation,comprehensive energy consumption is reduced by approximately 14%with product quality remaining comparable,and the operation indicators improve,compared to before the modification.In the background of reducing carbon emissions,pressure swing adsorption separation technology has an application advantage due to its lower comprehensive energy consumption compared to other technologies.

章海春;王一程;陈中明;张宏宇

中国石化扬子石油化工有限公司,江苏 南京 210048中国石油广西石化分公司,广西 钦州 535000西南化工研究设计院有限公司 国家碳一化学工程技术研究中心,工业排放气综合利用国家重点实验室,四川 成都 610225

化学工程

催化干气变压吸附分离技术乙烯回收

catalytic dry gaspressure swing adsorption separation technologyethylene recovery

《低碳化学与化工》 2024 (003)

73-78 / 6

10.12434/j.issn.2097-2547.20230192

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