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高压下二元富氢超导体的实验研究进展OA北大核心CSTPCD

Progress of Experimental Research on Binary Hydride Superconductors under High Pressure

中文摘要英文摘要

自从 1911 年著名物理学家Onnes发现超导电性以来,人们不断努力提高超导转变温度,室温超导体是人类追逐的百年梦想.在近百年的研究历程中,铜基超导体、铁基超导体及麦克米兰极限MgB2 超导体的发现不断刷新了人们对超导领域的认知,也增强了人们进一步提高超导转变温度和挖掘高温超导机制的信心.最近,理论预测并被实验验证的新型富氢化合物显示了高温乃至室温超导电性的巨大潜力,成为室温超导体的最佳候选体系之一.值得注意的是,高压下硫氢化物和镧氢化物均具有超过200 K的超导转变温度,引领了富氢化合物的研究热潮,涌现了一些重要的理论和实验成果.本文聚焦于目前富氢化合物超导体的实验研究进展,从不同氢结构单元及氢成键特征的角度总结和归纳新型富氢化合物的晶体结构性质及超导性能.主要介绍了 5 种在实验上成功获得的富氢化合物超导体:间隙型、离子型、共价型、笼型及分子型.通过对比分析不同类型的富氢化合物超导体,总结出一些影响超导转变温度的普适规律,并提出目前实验上亟待解决的问题和未来主攻的实验方向.

Since the discovery of superconductivity by the famous physicist Onnes in 1911,people have constantly tried to improve the superconducting transition temperature,and the room-temperature superconductors have also been a century-old dream of human beings.In the course of nearly a hundred years of research,it has constantly updated people's understanding of superconductivity,enhanced people's confidence in further improving the superconducting transition temperature and exploring the mechanism of high temperature superconductivity that scientists have discovered copper based superconductors,iron based superconductors and McMillan limit superconductors(like MgB2).Recently,new hydrogen-rich compounds predicted theoretically and verified experimentally have shown great potential for high temperature superconductivity even room temperature superconductivity,becoming one of the best candidates for room temperature superconductors.It is worth noting that some sulfur hydrides and lanthanum hydrides have superconductivity of more than 200 K under high pressure,leading a research boom of hydrogen-rich compounds and some important theoretical and experimental results have emerged.This paper focuses on the current research progress of hydrogen-rich superconductors,summarizes the crystal structure properties and superconducting properties of new hydrogen-rich compounds from the perspective of different hydrogen structural units and hydrogen bonding characteristics.Five kinds of superconductors in hydrogen-rich compounds are introduced in this paper:interstitial type,ionic type,covalent type,cage type and molecular type,and some general rules affecting the superconducting transition temperature are summarized through comparative analysis of different types of hydrogen-rich compound superconductors.In the end,the current experimental problems to be solved and the future experimental direction are put forward.

郭鉴宁;王煜龙;朱程程;黄晓丽;崔田

吉林大学物理学院, 吉林 长春 130012吉林大学物理学院, 吉林 长春 130012||宁波大学物理科学与技术学院, 浙江 宁波 315211

高压超导富氢化合物金刚石对顶砧共价型氢化物笼型氢化物分子型氢化物

high-pressure superconductivityhydrogen-rich compounddiamond anvil cellcovalent hydrideclathrate hydridemolecular hydride

《高压物理学报》 2024 (002)

高压下镧系稀土金属富氢化物结构及超导电性研究

10-31 / 22

国家自然科学基金(11974133,52072188);国家重点研发计划(2022YFA1405500);长江学者和高校创新研究团队计划(IRT_15R23);浙江省科技创新团队(2021R01004)

10.11858/gywlxb.20230742

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