高压物理学报2024，Vol.38Issue(2)：10-31,22.DOI:10.11858/gywlxb.20230742
高压下二元富氢超导体的实验研究进展
Progress of Experimental Research on Binary Hydride Superconductors under High Pressure
摘要
Abstract
Since the discovery of superconductivity by the famous physicist Onnes in 1911,people have constantly tried to improve the superconducting transition temperature,and the room-temperature superconductors have also been a century-old dream of human beings.In the course of nearly a hundred years of research,it has constantly updated people's understanding of superconductivity,enhanced people's confidence in further improving the superconducting transition temperature and exploring the mechanism of high temperature superconductivity that scientists have discovered copper based superconductors,iron based superconductors and McMillan limit superconductors(like MgB2).Recently,new hydrogen-rich compounds predicted theoretically and verified experimentally have shown great potential for high temperature superconductivity even room temperature superconductivity,becoming one of the best candidates for room temperature superconductors.It is worth noting that some sulfur hydrides and lanthanum hydrides have superconductivity of more than 200 K under high pressure,leading a research boom of hydrogen-rich compounds and some important theoretical and experimental results have emerged.This paper focuses on the current research progress of hydrogen-rich superconductors,summarizes the crystal structure properties and superconducting properties of new hydrogen-rich compounds from the perspective of different hydrogen structural units and hydrogen bonding characteristics.Five kinds of superconductors in hydrogen-rich compounds are introduced in this paper:interstitial type,ionic type,covalent type,cage type and molecular type,and some general rules affecting the superconducting transition temperature are summarized through comparative analysis of different types of hydrogen-rich compound superconductors.In the end,the current experimental problems to be solved and the future experimental direction are put forward.关键词
高压超导/富氢化合物/金刚石对顶砧/共价型氢化物/笼型氢化物/分子型氢化物Key words
high-pressure superconductivity/hydrogen-rich compound/diamond anvil cell/covalent hydride/clathrate hydride/molecular hydride分类
数理科学引用本文复制引用
郭鉴宁,王煜龙,朱程程,黄晓丽,崔田..高压下二元富氢超导体的实验研究进展[J].高压物理学报,2024,38(2):10-31,22.基金项目
国家自然科学基金(11974133,52072188) （11974133,52072188）
国家重点研发计划(2022YFA1405500) （2022YFA1405500）
长江学者和高校创新研究团队计划(IRT_15R23) （IRT_15R23）
浙江省科技创新团队(2021R01004) （2021R01004）
