燃料化学学报（中英文）2024，Vol.52Issue(4)：481-495,15.DOI:10.1016/S1872-5813(23)60401-3
生物质与塑料共催化热解制备芳烃化合物研究进展
Review on the progress in the production of aromatic hydrocarbons by co-catalytic pyrolysis of biomass and plastics
摘要
Abstract
Aromatic hydrocarbons,especially monocyclic aromatic hydrocarbons such as benzene,toluene,and xylene(BTX),are important basic raw materials in the chemical industry,which are mainly derived from the catalytic reforming and thermal cracking of fossil fuels.The co-catalytic pyrolysis of biomass and plastic to produce aromatics has the advantages of high efficiency,environmental protection,low cost,and high selectivity.It can solve the problems of pyrolysis products such as high oxygen content,low aromatics yield,and low selectivity,which are caused by the characteristics of biomass rich in oxygen and poor in hydrogen.This article reviewed the research progress of co-catalytic pyrolysis of biomass and plastics to prepare aromatic compounds.Firstly,the types of raw materials for co-catalytic pyrolysis were introduced,and then the co-catalytic pyrolysis catalysts were emphasized.The reaction mechanisms of co-catalytic pyrolysis of biomass and plastics,such as the synthesis of dienes and hydrocarbon pool synergy were summarized.Finally,the future research focus and development direction of co-catalytic pyrolysis of biomass and plastics were proposed,which is developing the highly active and stable modified molecular sieve catalysts in order to improve the aromatics yield.关键词
生物质/塑料/共催化热解/芳烃/催化剂Key words
biomass/plastic/co catalytic pyrolysis/aromatic hydrocarbon/catalyst分类
能源科技引用本文复制引用
韩冬,司洪宇,华栋梁,孙来芝,陈雷,杨双霞,李天津,谢新苹,许美荣,唐文东,赵保峰..生物质与塑料共催化热解制备芳烃化合物研究进展[J].燃料化学学报（中英文）,2024,52(4):481-495,15.基金项目
The project was supported by the Natural Science Foundation of Shandong Province(ZR2023MB040,ZR2022MB059,ZR2021QB156),the Key Research and Development Program of Shandong Province(2022CXGC010701),Shandong Province Science and Technology Small and Medium Enterprises Improvement Project(2023TSGC0460),Jinan City's"20 New Colleges and Universities"project(202228018,2021GXRC053),the Education and Industry Integration Innovation Pilot Project(2022JBZ02-03,2023PX086,2022PX009).山东省自然科学基金(ZR2023MB040,ZR2022MB059,ZR2021QB156),山东省重点研发计划(重大科技创新工程)(2022CXGC010701),山东省科技型中小企业提升项目(2023TSGC0460),济南市"新高校20条"项目(202228018,2021GXRC053)和科教产融合试点工程项目(2022JBZ02-03,2023PX086,2022PX009)资助 （ZR2023MB040,ZR2022MB059,ZR2021QB156）
