废弃熔融石英玻璃高温晶化为方石英的过程研究OA北大核心CSTPCD
Study on the process of converting waste fused quartz glass into cristobalite by nucleation crystallization at high temperature
高纯熔融石英玻璃当前被广泛应用于高新产业中,但是在使用过程中,由于析晶、软化变形等情况导致高纯熔融石英玻璃产品不能继续使用.本文在对废弃熔融石英玻璃的物相、杂质、气泡等分析的基础上,采用高温物相转化将废弃熔融石英玻璃转化为方石英,讨论了煅烧温度、保温时间、粒径三个影响因素,通过Jade软件计算了高温物相转化产物的晶相含量占比.结果表明,废弃熔融石英玻璃经过高温焙烧处理后转化为方石英相,并且方石英的含量主要受煅烧温度、保温时间和颗粒粒径的影响,随着煅烧温度升高和保温时间的延长,颗粒粒径越小,方石英的含量也逐渐增加.从1230℃开始,废弃熔融石英玻璃开始成核结晶,在1480℃进入一个快速结晶期,在1500℃可完全转化为方石英相.
At present,high purity fused quartz glass is widely used in high-tech industry,however,crystalli-zation,softening and deformation due to long-term use all affect its performance.In this paper,the waste fused quartz glass was transformed into cristobalite by high temperature phase transformation based on the analysis of the phase,impurities and bubbles of the waste fused quartz glass,and the three influencing factors including calcination temperature,holding time and particle size were discussed.The crystal phase content proportion of the product was theoretically calculated by Jade software.The results showed that the waste fused quartz glass was transformed into cristobalite phase after high temperature roasting,and the content of cristobalite was mainly affected by the calcination temperature,holding time and particle size.With the in-creases of calcination temperature and extension of holding time,and the decrease the particle size,the con-tent of cristobalite increased gradually.At 1230℃,the waste molten quartz glass began to nucleate and crys-tallize.It entered a rapid crystallization period at 1480℃and was completely transformed into a cristobalite phase at 1500℃.
游敦翰;孙红娟;彭同江;刘波;王振轩
西南科技大学固体废物处理与资源化教育部重点实验室, 绵阳 621010||西南科技大学矿物材料及应用研究所, 绵阳 621010西南科技大学矿物材料及应用研究所, 绵阳 621010
环境科学
废弃熔融石英玻璃方石英高温物相转化煅烧温度
Waste fused quartz glassCristobaliteHigh temperature phase transformationCalcination tem-perature
《四川大学学报(自然科学版)》 2024 (002)
136-142 / 7
四川省知识产权局知识产权专项资金项目(2022-ZS-00031)
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