化工进展2024，Vol.43Issue(3)：1224-1231,8.DOI:10.16085/j.issn.1000-6613.2023-0417
具有高浓度氨腔室的立式热再生氨电池性能特性
Performance of a vertical thermally regenerative ammonia-based battery with a high-concentration ammonia chamber
摘要
Abstract
Thermally regenerative ammonia-based battery(TRAB)can effectively convert low-temperature thermal energy into electricity,but its serious ammonia crossover phenomenon seriously affects the power production stability of the battery.A vertical thermally regenerative ammonia-based battery with a high-concentration ammonia chamber(TRAB-C)was developed based on the phenomenon of ammonia crossover and stratification in this study.The construction of high-concentration ammonia chamber and the block layer of ammonia transfer was applied to adjust ammonia distribution and then alleviate ammonia crossover.At a higher ammonia concentration(≥6mol/L),TRAB-C obtained higher output power,higher total charge,and more stable power generation capacity than a TRAB with a conventional structure because it solved the ammonia crossover by regulating the distribution of ammonia concentration in the anode.In addition,the porous copper foam anode could block the downward transport of ammonia to alleviate ammonia crossover further.A porous electrode with appropriate pore density(80PPI)induced a large electrode surface area and favorable mass transfer inside the electrode,contributing to the maximum power(10.8mW)of TRAB-C.关键词
热再生氨电池/高浓度氨腔室/产电稳定性/最大输出功率/氨渗透Key words
thermally regenerative ammonia-based battery/high-concentration ammonia chamber/power generation stability/maximum power/ammonia crossover分类
信息技术与安全科学引用本文复制引用
卢志强,石雨,陈鹏宇,张亮,李俊,付乾,朱恂,廖强..具有高浓度氨腔室的立式热再生氨电池性能特性[J].化工进展,2024,43(3):1224-1231,8.基金项目
国家自然科学基金创新研究项目(52021004) （52021004）
国家自然科学基金面上项目(51976018) （51976018）
重庆市自然科学基金面上项目(CSTB2022NSCQ-MSX1596) （CSTB2022NSCQ-MSX1596）
重庆归国留学人员科研基金(cx2021088). （cx2021088）
