C4烯烃转化制丙烯工艺及催化剂研究OA北大核心

Objective To develop the process of catalytic cracking of C4 olefins to propylene and the catalyst preparation technology,the pilot test and industrial side line test are completed.Methods The fixed-bed evaluation apparatus was used to investigate the impact of catalyst formulation,modification,and industrial conditions on catalyst activity,selectivity,and stability.Results The catalyst with ZSM-5 zeolite as the active component had good activity,selectivity,stability and regeneration performance in the conversion of C4 olefins to propylene.The introduction of phosphorus did not change the crystal structure of the catalyst,but it reduced the number of acidic sites on the catalyst,and adjusted the molar ratio of B acid and L acid of ZSM-5 zeolite.With the increase of phosphorus loading to 5 wt％,the interaction between phosphorus and aluminum in molecular sieves was gradually strengthened,and phosphorus could interact with framework aluminum and non-framework aluminum.Conclusions The conversion rate of C4 olefins is more than 80％,the selectivity of propylene is 35％-45％,the once-through life of catalyst is more than one month,and the regeneration recovery rate is 95％.