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La2Ce2O7/YSZ复合热障涂层制备及高热循环寿命机理研究

亢永霞 谌帅 齐晓涵 汤金博 田雨晶 张漩

机电工程技术2024,Vol.53Issue(4):184-187,4.
机电工程技术2024,Vol.53Issue(4):184-187,4.DOI:10.3969/j.issn.1009-9492.2024.04.040

La2Ce2O7/YSZ复合热障涂层制备及高热循环寿命机理研究

Preparation of La2Ce2O7/YSZ Composite Thermal Barrier Coating and Its Mechanism of High Thermal Cycling Lifetime

亢永霞 1谌帅 1齐晓涵 1汤金博 1田雨晶 1张漩1

作者信息

  • 1. 西安工程大学材料工程学院,西安 710048
  • 折叠

摘要

Abstract

La2Ce2O7(LC)/yttrium partially stabilized zirconia(YSZ)composite thermal barrier coating is deposited by supersonic plasma spraying technology to solve the problem of low thermal cycling lifetime of YSZ thermal barrier coating under CMAS corrosion.The double powder feeding mode is used to realize the composite of LC and YSZ,and the problem of sudden drop of the thermal expansion coefficient of LC material at low temperature is effectively solved based on the mutual influence of the residual stress between LC and YSZ.In addition,the composite coating has better thermal insulation performance and CMAS corrosion resistance.The CMAS corrosion resistance and thermal cycling failure behavior of LC/YSZ composite coating with CMAS corrosion are studied by high temperature static corrosion test and thermal cycling test.The results show that the thermal cycle life of LC/YSZ composite coating is nearly 90%higher than that of traditional YSZ coating,which can be attributed to the following three aspects:(1)mixing LC with YSZ can effectively eliminate the sudden decrease of thermal expansion coefficient of LC material at low temperature;(2)the thermal insulation performance of LC/YSZ composite coating is better than that of YSZ coating;(3)LC/YSZ composite coating can react with CMAS to form a reaction layer composed of La-Ce apatite phase,CaAl2Si2O8,m-ZrO2 and t-ZrO2 phases,which can prevent the penetration of CMAS melt effectively.

关键词

热障涂层/CMAS腐蚀/热循环失效

Key words

thermal barrier coatings/CMAS corrosion/thermal cycling failure

分类

矿业与冶金

引用本文复制引用

亢永霞,谌帅,齐晓涵,汤金博,田雨晶,张漩..La2Ce2O7/YSZ复合热障涂层制备及高热循环寿命机理研究[J].机电工程技术,2024,53(4):184-187,4.

基金项目

陕西省自然科学基础研究计划资助项目(2022JQ-319) (2022JQ-319)

陕西省大学生创新创业训练计划项目(S202210709090) (S202210709090)

机电工程技术

1009-9492

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