辐照降解魔芋葡甘聚糖产物的制备及结构表征OA北大核心CSTPCD
Preparation and Structural Characterization of Irradiation-Degraded Konjac Glucan Products
为促进魔芋葡甘聚糖(KGM)降解产物的高效利用,本研究围绕辐照对魔芋葡甘聚糖(KGM)降解产物的影响展开,比较不同辐照剂量处理下魔芋葡甘聚糖(KGM)分子量、特征黏度、可溶性糖含量、电化学特性、外观色泽、微观及化学结构、晶体结构的变化.结果表明,与未辐照处理相比,KGM辐照降解产物的主链结构未改变,结晶区减弱;随着辐照剂量的增加,分子质量从未辐照处理的894.6 kDa降至32 kGy辐照处理的4.70 kDa,特征黏度及可溶性总糖含量降低;扫描电子显微镜结果显示,辐照降解产物呈片状且出现孔洞,组间Zeta电位差异显著.本试验结果可为KGM辐照降解改性和资源高效利用提供参考.
In order to promote the efficient utilization of the degradation products of konjac glucomannan(KGM),this research studied the effects of irradiation on the degradation products of KGM.The changes of molecular weight,intrinsic viscosity,soluble sugar content,electrochemical properties,appearance,color,microstructure,chemical structure,and crystal structure of(KGM were investigated under different irradiation doses.The results showed that there was no change in the main chain structure and weakened crystalline region of KGM irradiated degradation products compared with the unirradiated KGM.With irradiation dose increased,the KGM irradiated degradation products showed a decreased molecular mass from 894.6 to 4.70 kDa,as well as a decreasing trend of intrinsic viscosity and total soluble sugar content.SEM results showed that the irradiated degradation products of KGM were flaky and porous,and the Zeta potential was significantly changed.This work provided a strategy about the degradation and modification of KGM by irradiation for the efficient utilization of resources.
张婉;王雪莉;阙凤;汪兰;石柳;郭晓嘉;孙卫青;熊光权
长江大学生命科学学院,湖北 荆州 434000||湖北省农业科学院农产品加工与核农技术研究所/农业农村部农产品冷链物流技术重点实验室,湖北 武汉 430000湖北省农业科学院农产品加工与核农技术研究所/农业农村部农产品冷链物流技术重点实验室,湖北 武汉 430000长江大学生命科学学院,湖北 荆州 434000
魔芋葡甘聚糖辐照降解结构表征
konjac glucomannanirradiation degradationstructural characterization
《核农学报》 2024 (007)
1291-1297 / 7
湖北省农业科技创新中心2020重大科技研发专项(2020-620-000-002-03),2023年湖北省博士后创新实践岗位
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