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CF3H和CO2抑制CH4爆炸实验研究OA北大核心CSTPCD

Study on suppression of CH4 explosion by CF3H and CO2

中文摘要英文摘要

为对比研究CF3H和CO2 对CH4 爆炸特性的抑制效果,使用 20 L球型爆炸压力测试系统分别测量对比 2 种抑制剂对CH4 在空气中爆炸极限范围的影响;研究了不同体积分数的 2 种抑制剂对CH4 体积分数 9.5%爆炸压力参数影响,分析了 2 种抑制剂针对CH4 在空气中爆炸的爆炸三角形.结果表明:CF3H和CO2 均能缩小CH4 在空气中的爆炸极限范围,抑制CH4 至失爆所需CF3H和CO2 体积分数分别为 12.5%和 21.5%;对比抑制CH4 体积分数 9.5%的爆炸参数(反应峰值压力和升压速率),10%CF3H的抑爆能力是等量CO2 的 1.95 倍和 1.3 倍,但是低于体积分数 4%的CF3H单独使用时对CH4 爆炸存在微弱的促进作用;2 种抑制剂作用下的爆炸三角形显示 CF3H抑制下的可爆区域面积小于 CO2,安全区域内 CF3H的窒息比是 CO2 的57%.

To compare the inhibitory effects of HFC-23(CF3H)and CO2 on methane explosion characteristics,a 20 L spherical ex-plosion pressure testing system was used to measure the effects of two inhibitors on the explosion limit range of CH4 in air.The ef-fects of two inhibitors with different volume fractions on the explosion pressure parameters of 9.5%volume fraction CH4 were stud-ied,and the explosion suppression triangles of the two inhibitors for CH4 explosion in air were analyzed.The results indicate that both CF3H and CO2 can reduce the explosion limit range of methane in air,and the required volume fractions of CF3H and CO2 to suppress CH4 detonation are 12.5%and 21.5%,respectively.Compared the explosion suppression parameters(peak reaction pres-sure and pressure rise rate)that inhibit CH4 by volume fraction CH4,the explosion suppression ability of 10%CF3H is 1.95 times and 1.3 times that of an equal amount of 9.5%CO2,but CF3H with volume fraction of 4%has a weak promotion effect on the explosion of CH4 when it used alone.The explosion suppression triangle of the two inhibitors shows that the explosive area under CF3H sup-pression is smaller than CO2,and the suffocation ratio of CF3H in the safe area is 57%of CO2.

白洁琪;白纪成;梁运涛;王琳;宋双林;田富超

煤炭科学研究总院,北京 100013||中煤科工集团沈阳研究院有限公司,辽宁 抚顺 113122||煤矿安全技术国家重点实验室,辽宁 抚顺 113122平顶山天安煤业股份有限公司,河南 平顶山 467000煤炭科学研究总院,北京 100013

矿山工程

CH4爆炸瓦斯爆炸CO2CF3H爆炸极限抑爆剂爆炸压力爆炸三角形

methane explosiongas explosionCO2CF3Hexplosion limitsuppressantexplosion pressureexplosive triangle

《煤矿安全》 2024 (005)

122-130 / 9

国家自然科学基金面上资助项目(52174229,52174230)

10.13347/j.cnki.mkaq.20240180

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