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烃源岩中类胡萝卜烷系列化合物的检出及其地质意义OA北大核心CSTPCD

Detection and Geological Significance of Carotenoid-Derived Alkanes in the Source Rocks:A case of well Malu 1,Lucaogou Formation,Santanghu Basin

中文摘要英文摘要

[目的]γ-和β-胡萝卜烷属于类胡萝卜烷,广泛分布于沉积物和原油中,但是低碳数的类胡萝卜烷系列化合物在烃源岩中较为少见,γ-和β-胡萝卜烷以及低碳数类胡萝卜烷系列化合物的来源及其在地质载体中的指示意义尚不明确.[方法]基于三塘湖盆地马朗凹陷马芦1井芦草沟组12件代表性烃源岩样品,通过气相色谱—质谱、岩石热解、镜质体反射率、总有机碳分析,详细表征其地球化学特征,以此获得目标化合物的生源信息.[结果和结论]马芦1井芦草沟组烃源岩有机质丰度高、类型好、处于成熟阶段,并且这些烃源岩样品中富含γ-和β-胡萝卜烷以及低碳数(碳数范围为C13~C25)的类胡萝卜烷系列化合物.根据正构烷烃、萜烷、甾烷等系列生物标志化合物的分布特征,并综合分析其他地球化学参数,认为γ-和β-胡萝卜烷主要来源于细菌.此外,结合烃源岩热演化、微生物化石及火山爆发的证据,提出低碳数类胡萝卜烷系列化合物可能是γ-和β-胡萝卜烷受微生物或热演化作用的产物,该研究可以为探索烃源岩的有机质来源、沉积环境和热演化程度提供新的思路.

[Objective]Both γ-carotane and β-carotane are carotenoid-derived alkanes,which are widely distribut-ed in sediments and crude oil,but carotenoid-derived alkanes with low carbon number are rare in the study of source rocks.This study explored the sources of γ-carotane,β-carotane and carotenoid-derived alkanes with low carbon numbers,indicating their significance in geological carriers.[Methods]Twelve representative source rock samples were collected from well Malu 1 in the Lucaogou Formation of the Malang Sag,Santanghu Basin.The geochemical characteristics were demonstrated in detail by gas chromatography-mass spectrometry,rock pyrolysis,vitrinite reflec-tance(Ro),and total organic carbon(TOC)analysis to obtain the biogenic information of the target compound.[Re-sults and Conclusions]The source rocks of the Lucaogou Formation from well Malu 1 are rich in organic matter,good in type,and in the mature stage.Moreover,the source rocks are rich in γ-and β-carotane with high abundance and have carotenoid-derived alkanes with low carbon number(Carbon number ranges from C13 to C25).Based on the comprehensive analysis of the distribution characteristics of a series of biomarkers such as n-alkanes,terpanes,and steranes,bacteria may be the main biological precursors of γ-and β-carotane.In addition,combining the evidence of thermal evolution of hydrocarbon source rocks,microbial fossils,and volcanic eruptions,the present study proposes that the carotenoid-derived alkanes with low carbon number may be the products of γ-and β-carotane affected by microorganisms or thermal evolution.This study provides new insights the exploration of organic matter source,sedimentary environment and thermal maturation of source rocks.

符印;王作栋;张婷;王文军;李晓斌;王志勇

中国科学院西北生态环境资源研究院,甘肃省油气资源勘探与评价重点实验室,兰州 730000||中国科学院大学,北京 100049中国科学院西北生态环境资源研究院,甘肃省油气资源勘探与评价重点实验室,兰州 730000中国石油吐哈油田分公司勘探开发研究院,新疆哈密 839009

地质学

三塘湖盆地马朗凹陷芦草沟组γ-和β-胡萝卜烷类胡萝卜烷系列化合物

Santanghu BasinMalang SagLucaogou Formationγ-and β-carotanecarotenoid-derived alkanes

《沉积学报》 2024 (003)

1092-1106 / 15

国家自然科学基金项目(42272187,42102195)[Foundation:National Natural Science Foundation of China,No.42272187,42102195]

10.14027/j.issn.1000-0550.2024.013

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