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定向凝固Cu-50%Sn包晶合金显微组织演变OA

Microstructure Evolution of Directionally Solidified Cu-50%Sn Peritectic Alloy

中文摘要英文摘要

随着科学技术的进步,越来越多的包晶合金因其优良性能广泛应用于工业生产领域,比如Fe-Cr-Ni、Ti-Al、Nd-Fe-B合金以及应用于电子封装领域的Cu-Sn合金等.随着电子信息产业向微型化和多功能化方向发展,对集成电路的机械、电子和热性能提出了更高的要求.本文以Cu-50%Sn(原子分数)包晶合金(L+Cu3Sn→Cu6Sn5)作为研究对象,通过布里奇曼定向凝固法,在显微镜下对组织进行观察和测量,研究淬火固液界面的凝固组织随凝固条件改变而产生的变化.生长距离、温度梯度一定时,随着生长速度的增大,初生相Cu3Sn经历了胞状→胞/枝状→枝晶状组织转变,Cu3Sn相的尺寸与间距均随生长速度的增大而减小;生长速度、生长距离一定时,随着温度梯度的增大,初生相Cu3Sn相由块状与枝晶状转变为胞状组织;生长速度、温度梯度一定时,随着生长距离的增大,初生相Cu3Sn由块状与胞/枝状转变为胞状组织,且Cu3Sn相尺寸发生小幅细化.基于上述实验结果,绘制了关于生长速度、温度梯度及生长距离条件下的显微组织选择图,进一步阐明了凝固条件的改变对Cu-50%Sn(原子分数)包晶合金显微组织的影响.

With the progress of science and technology,an increasing number of peritectic alloys,such as Fe-Cr-Ni,Ti-Al,and Nd-Fe-B alloys and Cu-Sn alloys for eletronic packaging,are being widely used in industrial production fields because of their excellent properties.With the development of the electronic information industry towards miniaturization and multifunctionality,higher requirements are put forward for the mechanical,electronic and thermal properties of integrated circuits.In this paper,Cu-50 at.%Sn peritectic alloy(L+Cu3Sn→Cu6Sn5)was used as the research object.The Bridgman directional solidification method was used to observe and measure the microstructure under a microscope.When the growth distance and temperature gradient are constant,with increasing growth rate,the primary phase Cu3Sn undergoes a transformation from a cellular → cellular/dendritic → dendritic structure,and the size and spacing of the Cu3Sn phase decrease.When the growth rate and growth distance are constant,the primary phase Cu3Sn changes from a block and dendrite to a cellular structure with increasing temperature gradient.When the growth rate and temperature gradient are constant,with increasing growth distance,the primary phase Cu3Sn changes from block and cell/dendritic to cellular structure,and the size of the Cu3Sn phase is slightly refined.Based on the above experimental results,a diagram of the microstructure under different growth rates,temperature gradients and growth distances was drawn,and the influence of the solidification conditions on the microstructure of the Cu-50 at.%Sn peritectic alloy are further clarified.

彭鹏;刘林;喻杨新;甘露;杨文超;徐远丽

兰州大学材料与能源学院,甘肃兰州 730000||西北工业大学凝固技术国家重点实验室,陕西西安 710072西北工业大学凝固技术国家重点实验室,陕西西安 710072兰州大学材料与能源学院,甘肃兰州 730000

金属材料

定向凝固包晶合金凝固组织金属间化合物

directional solidificationperitectic alloysolidification microstructureintermetallic compound

《铸造技术》 2024 (006)

532-542 / 11

甘肃省科技重大专项(22ZD6GB019);凝固技术国家重点实验室开放课题(SKLSP202204)

10.16410/j.issn1000-8365.2024.4040

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