新型炭材料(中英文)2024,Vol.39Issue(3):458-482,25.DOI:10.1016/S1872-5805(24)60857-7
碳基材料的Z型和S型异质结光催化清洁能源综述
A review of carbon material-based Z-scheme and S-scheme hetero-junctions for photocatalytic clean energy generation
摘要
Abstract
Carbon materials,including carbon nanotubes/nanofibers,graphene,graphene oxide,reduced graphene oxide,graphyne,graphdiyne,carbon quantum dots and fullerenes,have received considerable attention in recent years because of their unique properties such as high conductivity,excellent stability and biocompatibility.The integration of these materials into Z-scheme and S-scheme heterojunctions has emerged as a transformative strategy to increase their photocatalytic efficiency for energy conver-sion applications.We first consider the fundamental principles of clean energy generation such as photocatalytic H2 generation and CO2 reduction,elucidating their respective mechanisms and advantages.Various types of carbon materials,their synthesis and con-struction of Z-scheme and S-scheme heterojunctions are then discussed,emphasizing their role in promoting charge separation,redu-cing recombination losses and extending the spectral response range.With a focus on solar energy production,recent advances in carbon-based Z-scheme and S-scheme heterojunctions are discussed and summarized for photocatalytic H2 generation and CO2 re-duction.Lastly,the current problems in the field of carbon-based photocatalysts are discussed with insights for the future develop-ment of this field.关键词
炭材料/异质结/Z型/S型/光催化/氢能材料Key words
Carbonaceous/Heterojunctions/Z-scheme/S-scheme/Photocatalysis/Hydrogen materials分类
化学化工引用本文复制引用
Sahil Rana,Amit Kumar,WANG Tong-tong,Gaurav Sharma,Pooja Dhiman,Alberto García-Penas..碳基材料的Z型和S型异质结光催化清洁能源综述[J].新型炭材料(中英文),2024,39(3):458-482,25.基金项目
This research was funded by the following grants,including the Key Research and Development Program of Shaanxi Province(No.2023-LL-QY-42),the Xi'an University of Architecture and Technology Research Initiation Grant Program(No.1960323102),and the Xi'an University of Architecture and Techno-logy Special Program for Cultivation of Frontier Inter-disciplinary Fields(No.1960523142). (No.2023-LL-QY-42)