明胶/魔芋葡甘聚糖相行为调控共混膜结构及在热封包装中的应用OA北大核心CSTPCD
Regulation of phase behavior in gelatin/konjac glucomannan blend films and application in heat-seal packaging
为探究蛋白质/多糖相行为与共混膜结构之间的关系.以明胶和魔芋葡甘聚糖为原料制备不同比例的共混膜,通过微观结构、热力学性能、机械性能、光学性能和耐水性能等检测指标,研究不同共混比例下的相分离对膜结构的影响.结果表明,当魔芋葡甘聚糖添加量为0.4%时,共混体系出现微观相分离,共混膜断裂伸长率和热封强度显著提高,分别达到12.5%和1 704.2 N/m,拉伸强度为30.9 MPa,水蒸气透过率降至最低.进一步采用共聚焦拉曼光谱仪和扫描电镜原位观察相分离,发现共混膜中分散相聚集颗粒的主要成分为魔芋葡甘聚糖,其颗粒尺寸和分布密度与相分离程度成正比.研究为利用多糖与蛋白质共混相行为调控膜结构,并在可食性热封包装材料中的应用提供技术参考.
In order to investigate the relationship between protein quality/polysaccharide phase behavior and blend film structure,Blend films of different proportions were prepared using gelatin and konjac glucomannan as raw materials,and the effects of phase separation under different blend proportions on film structure were studied by using microstructure,thermodynamic properties,mechanical properties,optical properties,and water resistance as detection indicators.The results show that at an addition of 0.4%of konjac glucomannan,micro-phase separation occurs in the blend system,the elongation at break and heat seal strength of the blend films were significantly improved by 12.5%and 1 704.2 N/m respectively,the tensile strength is 30.9 MPa,and the water vapor transmission rate drops to the lowest.Further observation of the phase separation using confocal Raman spectroscopy and in situ scanning electron microscopy reveal that the main component of the dispersed phase aggregates in the blend films is konjac glucomannan,and the particle size and distribution density are directly proportional to the degree of phase separation.This study provides a technical reference for the application of polysaccharide-protein blend behavior to regulate film structure in edible heat-seal packaging materials.
李琛;黄晓岚;金伟平;郭城;纪执立;李金玲
武汉轻工大学 食品科学与工程学院,武汉 430040
轻工业
明胶魔芋葡甘聚糖相分离热封性能共混膜
gelatinkonjac glucomannanphase separationheat-sealing performanceblend film
《包装与食品机械》 2024 (003)
8-17,24 / 11
湖北省重点研发计划项目(2023BBB068)
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