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淀粉基番茄红素复合物的酸碱稳定性及其降解动力学研究OA北大核心CSTPCD

Acid-base stability and degradation kinetics of Amylose-Lycopene Complexes

中文摘要英文摘要

为了研究直链淀粉-番茄红素复合物的酸碱稳定性及其降解动力学,基于紫外吸收光谱研究ALCs中番茄红素吸光度在不同比例二甲基亚砜中的变化,分析不同pH值对ALCs色泽和紫外吸收光谱的影响,对其降解动力学进行研究.结果显示,与二甲基亚砜:水混合溶剂相比,ALCs在二甲基亚砜溶剂中的特征吸收峰发生明显蓝移,番茄红素呈H型聚集.二甲基亚砜和水体积比为1:1时,在酸性和弱碱环境下,ALCs表现出较好的溶解性;当溶液pH>12后,ALCs出现絮凝沉降现象.ALCs在二甲基亚砜和二甲基亚砜:水=1:1中的降解均符合二级反应动力学,在pH值为2,7,12环境中的降解均符合零级反应动力学.ALCs在不同pH值环境下的半衰期为185.54 h(pH=2)>34.45 h(pH=12)>29.50 h(pH=7).研究为ALCs稳定环境的研究提供理论基础.

In order to study the acid-base stability and degradation kinetics of Amylose-Lycopene Complexes(ALCs),the changes in lycopene absorbance in ALCs in different ratios of dimethyl sulfoxide were studied based on UV visible absorption spectroscopy.The effects of different pH values on the color and UV visible absorption spectra of ALCs were analyzed,and their degradation kinetics were studied.The results show that compared with the mixed solvent of dimethyl sulfoxide and water,the characteristic absorption peak of ALCs in dimethyl sulfoxide solvent shows a significant blue shift;ALCs aggregate in an H-shaped manner in a dimethyl sulfoxide aqueous solution system.When the volume ratio of dimethyl sulfoxide to water is 1:1,ALCs exhibit good solubility in acidic and weakly alkaline environments;When the pH of the solution exceeds 12,ALCs exhibit flocculation and sedimentation phenomenon.The degradation of ALCs in dimethyl sulfoxide and dimethyl sulfoxide:water ratio of 1:1 follows second-order reaction kinetics,and the degradation in pH environments of 2,7,and 12 follows zero order reaction kinetics.The half-life of ALCs in different pH environments is 185.54 h(pH=2)>34.45 h(pH=12)>29.50 h(pH=7).The study provides a theoretical basis for the study of stable environments for ALCs.

孙世东;孟凯丽;赵文红

郑州科技学院 食品科学与工程学院,郑州 450064郑州医药健康职业学院 检验学院,郑州 450000河南工业大学 粮油食品学院,郑州 450000

轻工业

直链淀粉番茄红素酸碱稳定性降解动力学

amyloselycopeneacid-base stabilitydegradation kinetics

《包装与食品机械》 2024 (003)

39-44 / 6

国家重点研发计划项目(2016YFD0400200);广东省天然产物绿色加工与产品安全重点实验室开放基金项目(KL-2018-18)

10.3969/j.issn.1005-1295.2024.03.006

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