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以碱性氧化物为转化剂制备高枸溶性磷实验研究OA

Experimental Study on Preparation of High Citric Acid Soluble Phosphorus by Alkaline Oxide

中文摘要英文摘要

为了制备有益于澳洲坚果生长所需的高枸溶性磷肥,以低品位磷矿和淤渣酸为实验原料,制备了水溶性磷半成品.选用碱性氧化镁(苦土干粉)、氧化钙、黄磷炉渣和钙镁磷肥为转化剂,探究了不同用量转化剂对枸溶性磷含量和转化率的影响.结果表明:以碱性氧化镁作转化剂时,添加 12%(质量分数)氧化镁时的转化效果最佳,枸溶性磷质量分数为21.78%,转化率为69.18%;以碱性氧化钙作转化剂时,添加 16%(质量分数)氧化钙时的转化效果最佳,枸溶性磷质量分数为25.80%,转化率为75.61%;以碱性黄磷炉渣作转化剂时,添加20%(质量分数)黄磷炉渣时的转化效果最佳,枸溶性磷质量分数为 18.27%,转化率为 53.87%;以钙镁磷肥作转化剂时,添加25%(质量分数)钙镁磷肥时的转化效果最佳,枸溶性磷质量分数为 21.73%,转化率为55.15%.

To create a phosphate fertilizer that is rich in citrate-soluble content to aid in the growth of macadamia nuts,researchers utilized low-quality phosphate rock and muck acid to produce water-soluble phosphorus products.They then tested the impact of various conversion a-gents such as alkaline magnesium oxide,calcium oxide,yellow phosphorus slag,and calcium magnesium phosphate fertilizer on the citrate-soluble phosphorus levels and conversion rates.Results indicated that using alkaline magnesium oxide as the conversion agent with 12%added showed the best conversion effect,resulting in a citric acid soluble phosphorus content of 21.78%and a conversion rate of 69.18%.Similarly,using alkaline calcium oxide with 16%added as the conversion agent yielded the best results,with a citrate-soluble phosphorus content of 25.80%and a conversion rate of 75.61%.When alkaline yellow phosphorus slag was used as the conversion agent with 20%added,the best con-version effect was observed,resulting in a citric acid soluble phosphorus content of 18.27%and a conversion rate of 53.87%.Finally,using calcium magnesium phosphate fertilizer as the conversion agent with 25%added showed the best results,with a citric acid soluble phosphorus content of 21.73%and a conversion rate of 55.15%.

师永林;李莹莹;孙玉翠;李恒;杨大润

云南云天化股份有限公司,云南 昆明 650228

化学工程

碱性氧化物转化剂枸溶性磷转化率

Alkaline oxidesConversion agentCitric acid soluble phosphorusConversion rate

《云南化工》 2024 (006)

45-48 / 4

云南省重大科技专项计划(202202AE090034)洱海流域农业高质量发展与面源污染防控协同的创新模式构建与示范.

10.3969/j.issn.1004-275X.2024.06.11

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