低碳化学与化工2024，Vol.49Issue(7)：34-41,8.DOI:10.12434/j.issn.2097-2547.20230294
CO2捕集中有机胺吸收剂的金属腐蚀研究进展
Research progress on metal corrosion of organic amine absorbents for CO2 capture
赵兴雷 1李璐蕊 2叶舣 1孙伟 1吕建辉1
作者信息
- 1. 中国石油集团安全环保技术研究院有限公司,北京 102206
- 2. 中国石油集团安全环保技术研究院有限公司,北京 102206||北京化工大学 化学工程学院,北京 100029
- 折叠
摘要
Abstract
The solvent method for CO2 capture has the advantages of mature technology and low cost,and is widely used.As commonly used absorbents,organic amines have the advantages of fast absorption rate and large absorption capacity.However,due to the chemical reaction between organic amines and CO2,the solution becomes corrosive,resulting in corrosion of equipment pipelines.The corrosion mechanism of organic amine solutions was reviewed.Hydrogenated amine ions,bicarbonate ions and water molecules are the main oxidants,which provide conditions for the occurrence of corrosion.The effects of the types and concentrations of organic amine solution,CO2 loadings,temperatures,O2 content and degradation products on the corrosiveness of the solution were discussed.Among them,CO2 loadings and temperatures are the main factors.The methods of using inorganic and organic corrosion inhibitors,adjusting the pH value of the solution and using stainless steel materials were summarized.The organic corrosion inhibitors for amine solutions are more worthy value of attention.The development direction of future corrosion inhibition technology was put forward.It is necessary to develop new corrosion inhibitors and combine them with corrosion resistant materials,which can provide a reference for further research and solving the corrosion problem of organic amine solutions.关键词
CO2捕集/有机胺吸收剂/腐蚀机理/缓蚀技术Key words
CO2 capture/amine absorbent/corrosion mechanism/corrosion inhibition technology分类
矿业与冶金引用本文复制引用
赵兴雷,李璐蕊,叶舣,孙伟,吕建辉..CO2捕集中有机胺吸收剂的金属腐蚀研究进展[J].低碳化学与化工,2024,49(7):34-41,8.
