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氟化碳(CFx)材料在锂原电池中的研究进展与应用OA北大核心CSTPCD

Research progress and applications of fluorocarbon (CFx) materials in lithium primary batteries

中文摘要英文摘要

CFx作为一种重要的正极材料,在锂原电池中具有高能量密度、长贮存寿命和优异的安全性等优点.近年来,研究人员通过研究Li/CFx的工作机理,揭示了CFx材料目前存在的问题,并针对这些问题进行了一系列的改性处理,如等离子体处理、表面包覆、原子掺杂等.此外,研究人员还通过表面脱氟、纳米尺度工程等手段,改变表面结构从而提升导电性和锂离子传输速率,进一步提高了其能量密度.这些研究成果为CFx在锂原电池中的应用提供了新的思路和途径.主要介绍了Li/CFx电池的工作机理及CFx材料目前存在的问题,针对CFx材料的改性方法做了总结分析,并对Li/CFx电池在航空航天、国防军事等领域的应用做了详细介绍和展望.

CFx serves as an important positive electrode material,has high energy density,long stor-age life,and excellent safety in lithium primary batteries. In recent years,researchers have identified the problems existing in CFx materials by studying the working mechanism of Li/CFx and have car-ried out a series of modification treatments based on these issues,such as plasma treatment,surface coating,and atomic doping. Furthermore,researchers have also changed the surface structure through methods like surface defluorination and nanoscale engineering to enhance conductivity and lithium ion transport rate,further improving its energy density. These research achievements provide new insights and approaches for the application of CFx in lithium primary batteries. This article mainly introduced the working mechanism of Li/CFx batteries and the current issues with CFx materi-als,summarized and analyzed the modification methods for CFx materials,and provided a detailed introduction and outlook on the applications of Li/CFx batteries in aerospace,national defense,and military fields.

张洋;张雅婷;张泽峰;王九洲;付甜甜

中国电子科技集团公司第十八研究所,天津300384天津大学,天津300072中国电子科技集团公司第十八研究所,天津300384||哈尔滨工程大学烟台研究院,山东烟台265502

动力与电气工程

氟化碳正极材料锂氟化碳电池改性方法

fluorocarbonpositive electrode materiallithium fluorocarbon batterymodification methods

《电源技术》 2024 (008)

1466-1474 / 9

10.3969/j.issn.1002-087X.2024.08.007

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