食品与机械2024，Vol.40Issue(10)：62-67,6.DOI:10.13652/j.spjx.1003.5788.2023.81117
超高效液相色谱—串联质谱法测定植物油中甲胺磷残留量的不确定度评定
Evaluation of uncertainty in determination of methamidophos residue in vegetable oil by ultra-performance liquid chromatography-tandem mass spectrometry
摘要
Abstract
[Objective]To evaluation the uncertainty of determination of methamidophos residues in vegetable oil by ultra-performance liquid chromatography-tandem mass spectrometry.[Methods]A vegetable oil sample was detected by ultra-high performance liquid chromatography-tandem mass spectrometry,and the recovery rate was determined at the same time.By analyzing the sources of uncertainty in the experimental process,the measurement uncertainty was ultimately evaluated.[Results]The residue amount of methamidophos in olive oil samples was not detected,and the uncertainty of the accuracy 1 sample was evaluated,The results were(0.018±0.010)mg/kg.[Conclusion]In the uncertainty measurement process of methamidophos residue in vegetable oil,the influence of standard curve fitting,ultra-high liquid chromatography-mass spectrometry,and standard working solution is relatively large,while the influence of sample weighing,sample pretreatment,and sample repeatability determination is relatively small.关键词
植物油/甲胺磷/液相色谱—串联质谱法/不确定度Key words
vegetable oil/methamidophos/liquid chromatography-tandem mass spectrometry/uncertainty引用本文复制引用
高含,刘锐,姜铖,王飞飞..超高效液相色谱—串联质谱法测定植物油中甲胺磷残留量的不确定度评定[J].食品与机械,2024,40(10):62-67,6.基金项目
平台建设专项(云南实验室建设)(编号:2022YKZY001) （云南实验室建设）
