电子元件与材料2025,Vol.44Issue(7):760-766,773,8.DOI:10.14106/j.cnki.1001-2028.2025.0133
碳微管纤维布负载ReS2用于钠离子电池低成本负极
Carbonmicrotube fiber cloth-supported ReS2 as a low-cost anode for sodium-ion batteries
摘要
Abstract
Self-supported carbon cloth electrodes show great potential in the developing low-cost sodium-ion batteries(SIBs).Rhenium disulfide(ReS2),with its high theoretical capacity,has attracted much attention.However,its low electrical conductivity severely affects the electrochemical performance.To address this challenge,a low-cost carbon microtube(CMT)fiber cloth was designed to replace the traditional metal current collectors(copper/aluminum foils),and a hydrothermal self-assembly process was utilized to in-situ construct a composite structure of ReS2 nanospheres on the CMT surface(CMT@ReS2@C).The rapid electron transport was facilitated by 3D conductive network in the CMT fiber cloth,while the electrolyte infiltration was enhanced by its porous structure.Furthermore,the structural volume expansion during repeated charge/discharge cycles was effectively mitigated by the synergistic interaction between ReS2 and the carbon microtube fiber cloth.Benefiting from these advantages,the CMT@ReS2@C anode demonstrates superior electrochemical performance in SIBs.Specifically,it retains a reversible capacity of 94 mAh·g-1 after 500 cycles at 1 A·g-1,with an average capacity decay rate of only 0.081%per cycle.关键词
碳微管纤维布/二硫化铼/负极材料/钠离子电池Key words
carbon microtube fiber cloth/rhenium disulfide/anode materials/sodium ion batteries分类
信息技术与安全科学引用本文复制引用
夏艳婷,李千年,黄浩洋,许俊..碳微管纤维布负载ReS2用于钠离子电池低成本负极[J].电子元件与材料,2025,44(7):760-766,773,8.基金项目
国家自然科学基金面上项目(52271208,51972092) (52271208,51972092)