包装与食品机械2026，Vol.44Issue(4)：26-35,10.DOI:10.3969/j.issn.1005-1295.2026.04.003
灭螨醌在柑橘上的残留降解及膳食风险评估
Residual degradation and dietary risk assessment of acequinocyl on citrus
摘要
Abstract
To address the lack of data on the residual degradation dynamics and dietary intake risk of acequinocyl 15%EW on citrus fruits,field residue tests were carried out using orah,shatangju,and kumquat as test materials.A high-performance liquid chromatography-tandem mass spectrometry(HPLC-MS/MS)method was used to determine the residual degradation dynamics of acequinocyl and hydroxyacequinocyl in different citrus varieties,and a dietary risk assessment was conducted.The results showed that acequinocyl and hydroxyacequinocyl exhibited good linear relationships(R2>0.99)in different citrus matrices.The limits of detection were 1.7-3.9 μg/kg and 1.0-1.2 μg/kg,respectively;the limits of quantitation were 4.5-7.9 μg/kg and 2.0-3.2 μg/kg,respectively;the recoveries were 79.4%—90.4%and 79.5%—92.6%,respectively,with RSD values of 2.4%—9.2%and 2.0%—9.0%,respectively.Except for the pulp of Shatangju,the degradation patterns of the two compounds in other parts of the three citrus varieties conformed to first-order kinetics,with half-lives of 17.5-24.8 d and 20.0-43.3 d,respectively.On the 14th and 28th days after application,the total residues of acequinocyl in the whole fruit of the three citrus varieties were 0.042-0.077 mg/kg and 0.013-0.046 mg/kg,respectively.The chronic and acute dietary exposure risks for all age groups were 0.03%—0.78%and 0.19%—2.84%,respectively.This study provides basic data for the rational use of acequinocyl on citrus and the establishment of maximum residue limits.关键词
广西柑橘/灭螨醌/羟基灭螨醌/残留/膳食风险评估Key words
Guangxi citrus/acequinocyl/hydroxyacequinocyl/residue/dietary risk assessment分类
轻工纺织引用本文复制引用
王运儒,罗义灿,陈壮美,吴凤,刘力,梁宏合,邓有展,卢巧忆,秦玉燕..灭螨醌在柑橘上的残留降解及膳食风险评估[J].包装与食品机械,2026,44(4):26-35,10.基金项目
广西重点研发计划项目(桂科农AB241484036) （桂科农AB241484036）
广西自然科学基金项目(2026GXNSFAA00640980) （2026GXNSFAA00640980）
广西农业和乡村振兴人才培养支持专项(GXQNTJ242129) （GXQNTJ242129）
广西农业科学院基本科研业务专项(桂农科2026YT013) （桂农科2026YT013）
